摘要

A new Zn(II) compound, namely [Zn-3(oxa)(3)(bix)(3)](n) (1 H(2)oxa = oxalic acid, bix = 4,4'-bis(imidazol-1-ylmethyl) benzene), has been synthesized by the reactions of Zn(II) ions with H2oxa and bix ligands under hydrothermal conditions. Single-crystal X-ray analysis reveals that compound 1 features a 2D layer framework, which further extended into a 3D supramolecular framework via intermolecular hydrogen bonds. In addition, the luminescent property of 1 was also investigated in the solid state at room temperature.

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