Determination of the Molecular-Weight Characteristics of Polyacrylic Acid and Its Copolymer with Butyl Acrylate

作者:Sivtsov E V*; Yasnogorodskaya O G; Chernikova E V; Voznyakovskii A P
来源:Russian Journal of Applied Chemistry, 2010, 83(4): 728-731.
DOI:10.1134/S1070427210040282

摘要

A new procedure was suggested for pretreatment of polyacrylic acid and its copolymer with butyl acrylate with the aim of examining the molecular-weight distribution: chemical modification by esterification with benzyl alcohol. Conditions were chosen for turbidimetric titration of the resulting polymers. The results confirmed the efficiency of isopropanol as chain-transfer agent in copolymerization of acrylic acid with butyl acrylate. The molecular-weight characteristics of polyacrylic acid prepared by radical polymerization in water in the presence of Cu(II) ions were determined.

  • 出版日期2010-4

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