Alternating voltage induced electrochemical synthesis of three-dimensionalization copper oxide for lithium-ion battery application

作者：Jing, Mingjun; Ding, Zhiying^*; Hou, Hongshuai; Zhang, Yan; Zou, Guoqiang; Li, Simin; Ji, Xiaobo^*

来源：Chemical Physics Letters, 2016, 653: 30-34.

DOI：10.1016/j.cplett.2016.04.057

• Copper oxide
• Three-dimensional structures
• Single crystal nanosheets
• Alternating voltage
• Lithium-ion batteries

Three-dimensional copper oxide structures composed of single crystal nanosheets have been successfully prepared by a green electrochemical alternating voltage approach. This special structure of copper oxide grown along the [010] direction can be effective to accommodate the volume expansion during charge-discharge cycles. The obtained product as anode materials in lithium-ion batteries displays outstanding electrochemical performances with a high reversible capacity of 635.2 mA h g(-1) after 50 cycles at 100 mA g(-1) close to the theoretical capacity of copper oxide (674 mA h g(-1)).

• 出版日期2016-6-1
• 单位中南大学