科研之友
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摘要
The onset of hydrous partial melting in the mantle above the transition zone is dictated by the H2O storage capacity of peridotite, which is defined as the maximum concentration that the solid assemblage can store at P and T without stabilizing a hydrous fluid or melt. H2O storage capacities of minerals in simple systems do not adequately constrain the peridotite water storage capacity because simpler systems do not account for enhanced hydrous melt stability and reduced H2O activity facilitated by the additional components of multiply saturated peridotite. In this study, we determine peridotite-saturated olivine and pyroxene water storage capacities at 10-13 GPa and 1,350-1,450 degrees C by employing layered experiments, in which the bottom similar to 2/3 of the capsule consists of hydrated KLB-1 oxide analog peridotite and the top similar to 1/3 of the capsule is a nearly monomineralic layer of hydrated Mg# 89.6 olivine. This method facilitates the growth of similar to 200-mu m olivine crystals, as well as accessory low-Ca pyroxenes up to similar to 50 mu m in diameter. The presence of small amounts of hydrous melt ensures that crystalline phases have maximal H2O contents possible, while in equilibrium with the full peridotite assemblage (melt ? ol + pyx + gt). At 12 GPa, olivine and pyroxene water storage capacities decrease from similar to 1,000 to 650 ppm, and similar to 1,400 to 1,100 ppm, respectively, as temperature increases from 1,350 to 1,450 degrees C. Combining our results with those from a companion study at 5-8 GPa (Ardia et al., in prep.) at 1,450 degrees C, the olivine water storage capacity increases linearly with increasing pressure and is defined by the relation C-H2O(olivine)(ppm) = 57.6(+/-16) x P(GPa) - 169(+/-18). Adjustment of this trend for small increases in temperature along the mantle geotherm, combined with experimental determinations of D-H2O(pxy/olivine) from this study and estimates of D-H2O(gt/olivine) allows for estimation of peridotite H2O storage capacity, which is 440 +/- 200 ppm at 400 km. This suggests that MORB source upper mantle, which contains 50-200 ppm bulk H2O, is not wet enough to incite a global melt layer above the 410-km discontinuity. However, OIB source mantle and residues of subducted slabs, which contain 300-1,000 ppm bulk H2O, can exceed the peridotite H2O storage capacity and incite localized hydrous partial melting in the deep upper mantle. Experimentally determined values of D-H2O(pyx/olivine) 10-13 GPa have a narrow range of 1.35 +/- 0.13, meaning that olivine is probably the most important host of H2O in the deep upper mantle. The increase in hydration of olivine with depth in the upper mantle may have significant influence on viscosity and other transport properties.
- 出版日期2012-2
