Modulation of the Dielectric Properties of CaCu3Ti4O12 System with Gd-Substitution

作者:Zhen Ping Chen; Hui Fang He; Tao Li; Hai Yang Dai; Zhi Quan Chen
来源:Defect and Diffusion Forum, 2017, 4179: 213-216.
DOI:10.4028/www.scientific.net/DDF.373.213

摘要

To specify the effects of modulating mechanism of Gd substitution on the dielectric properties for Ca1- x Gd x Cu3Ti4O12 system, the XRD, SEM and positron positron annihilation technique have been implemented. The results display that both grain size and vacancy-type defect concentration play important roles in controlling the dielectric properties of CaCu3Ti4O12. The dielectric properties are improved by adding an appropriate amount of Gd additives ( x =0.01) but weakened by higher Gd doping content since this is closely related to the grain size and concentration of vacancy-type defect in the samples.