科研之友
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摘要
The rational design of small but highly functional artificial catalysts is very important for practical organic synthesis. Asymmetric Lewis acid catalyses with non-covalent secondary interactions have been developed for enantioselective reactions. This tutorial review describes the concept, design and examples of asymmetric Cu(II) catalyses for cycloaddition reactions based on intramolecular pi-cation or pi-cation interactions between the copper( II) cation and auxiliary Lewis basic sites of the chiral ligands.
- 出版日期2011
