9a-Hydroxy-3,8a-dimethyl-5-methylene-4,4a,5,6,9,9a-hexahydronaphtho[2,3- b]furan-2(8aH)-one

作者:Liu, Wen-Hong; He, Jie; Ding, Zhi-Shan; Song, Zhong-Cheng*; Zhan, Zha-Jun
来源:Acta Crystallographica Section E-Structure Reports Online, 2011, 67: O730-U2764.
DOI:10.1107/S1600536811006519

摘要

The title compound, C15H18O3, was isolated from Lactarius piperatus (Fr.) S. F. Gary collected from the Kunming area in Yunnan province, China. The central cyclohexyl ring adopts a chair conformation, while the furanone ring is close to planar (r.m.s. deviation = 0.0174 angstrom). The remaining methylene cyclohexene ring has a flattened chair conformation. In the crystal, molecules are linked via intermolecular O-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds into zigzag chains along the a axis.

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