Diazido(2,2 '-bipyridyl)dimethanolnickel(II)

作者:Li Hong Gang*; Li Shao Ying; Shao Li Jun
来源:Acta Crystallographica Section E-Structure Reports Online, 2010, 66: M1349-U148.
DOI:10.1107/S1600536810038377

摘要

The title complex, [Ni(N-3)(2)(C10H8N2)(CH3OH)(2)], lies on a twofold roation axis which runs through the Ni-II ion and the mid-point of the bipyridine ligand. The Ni-II ion is coordinated in a distorted octahedral environment by two azide ligands in a trans configuration. The methanol ligands are in a cis configuration and their hydroxy groups form intramolecular O-H center dot center dot center dot(N,N) hydrogen bonds with the azide ligands.

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