科研之友
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摘要
An efficient, convenient and mild Ru-catalyzed reductive amination reaction was developed by employing H2O as both hydrogen source and solvent via B-2(OH)(4)/H2O systems. The reaction proceeded smoothly under air at ambient temperature and exhibited excellent chemoselectivities toward unsaturated and heteroaromatic as well as aliphatic aldehydes. Interestingly, a-deuterated amines were also obtained expediently by employing D2O in our catalytic systems.
