A Cu coordination polymer-modified [V4O12]4- polyanion with interdigitated architecture

作者：Zhang, Peng-peng; Peng, Jun^*; Pang, Hai-jun; Chen, Yuan; Zhu, Min; Wang, Dan-dan; Liu, Ming-guan; Wang, Yong-hui

来源：Inorganic Chemistry Communications, 2010, 13(12): 1414-1417.

DOI：10.1016/j.inoche.2010.08.004

• Polyoxovanadates
• Interdigitated structure
• Hydrothermal synthesis
• Metal-organic polymer

A new compound, [Cu-4(bix)(3)V4O12] (1) (bix=1,4-Bis(imidazol-1-ylmethyl)benzene), has been hydrothermally synthesized, and characterized by elemental analyses, IR spectroscopy, thermogravimetric analysis, and single X-ray diffraction. In the structure of compound 1, the 2D layer is constructed from the ladder-like chains in which the [V4O12](4-) polyanions act as the middle rails. The whole structure exhibits an interdigitated architecture which is unusual in the polyoxometalate family. Further, the electrochemistry property of the compound is studied.

• 出版日期2010-12
• 单位东北师范大学