An efficient metal- and solvent-free organocatalytic system for chemical fixation of CO2 into cyclic carbonates under mild conditions

作者：Wang, Lin; Zhang, Guangyou; Kodama, Koichi; Hirose, Takuji^*

来源：Green Chemistry, 2016, 18(5): 1229-1233.

DOI：10.1039/c5gc02697k

• ORGANIC CARBONATES
• PROPYLENE CARBONATE
• HOMOGENEOUS CATALYST
• IONIC LIQUID
• DIOXIDE
• EPOXIDES
• TRANSFORMATION
• CYCLOADDITION
• COMPLEXES
• HALIDES

An efficient, metal- and solvent-free catalytic system was developed for the conversion of CO2 and epoxides to the corresponding cyclic carbonates under mild conditions (T = 25-45 degrees C, 1 atm CO2) in high-to-excellent yields. The catalyst could be easily recycled, providing a more sustainable process for the chemical fixation of CO2.

• 出版日期2016
• 单位济南大学