Addition of N-Acyliminium Ion Pools to Alkenes Having a Nucleophilic Moiety: Integration of Intermolecular and Intramolecular Reactions

作者:Ashikari Yosuke; Kiuchi Yohei; Takeuchi Tomoya; Ueoka Koji; Suga Seiji; Yoshida Jun ichi*
来源:Chemistry Letters, 2014, 43(2): 210-212.
DOI:10.1246/cl.130947

摘要

The reaction of electrochemically generated N-acyliminium ion pools with alkenes bearing a heteroatom nucleophilic functionality such as a hydroxy group, a carboxy group, and an oxime moiety led to intermolecular carbon carbon bond formation followed by intramolecular carbon heteroatom bond formation to give the corresponding heterocyclic compounds such as cyclic ethers, lactones, and 2-isoxazolines, respectively.

  • 出版日期2014-2-5