A trigonal prismatic Cu-6-pyrazolato complex containing a mu(6)-F ligand

作者：Mathivathanan Logesh; Al Ameed Karrar; Lazarou Katerina; Travnicek Zdenek; Sanakis Yiannis; Herchel Radovan^*; McGrady John E; Raptis Raphael G

来源：Dalton Transactions, 2015, 44(47): 20685-20691.

DOI：10.1039/c5dt03892h

The encapsulation of a fluoride ion in a trigonal prismatic Cu-6(II)-pyrazolato cage results in a small expansion of the Cu-6-host. The structural, electronic and magnetic features of the Cu-6-complex, containing an endohedral fluoride in the rare mu(6)-F coordination mode, are compared with those of the parent complex with a vacant Cu-6-cage.

• 出版日期2015