Wonderful nanoconfinement effect on redox reaction equilibrium

作者:Patra Sabyasachi; Pandey Ashok K; Sarkar Sudip K; Goswami A*
来源:RSC Advances, 2014, 4(63): 33366-33369.
DOI:10.1039/c4ra05104a

摘要

Polyol and other routes of reduction of noble metal ions that are not feasible under ambient condition have been observed with appreciable rate in nanoconfined spaces of solid matrices for the first time. Also a remarkable enhancement of the rate constant/activity parameter has been observed for AgNPs catalyzed BH4- reduction of p-nitrophenol in nanoscale confinement.

  • 出版日期2014