An organotin coordination polymer formed from 1,4-bis(pyridin-3-yl-methoxy) benzene and dibenzyl-dichlorostannane

作者:Li Shun Li; Liu Jie; Ma Jian Fang*
来源:Acta Crystallographica Section E-Structure Reports Online, 2007, 63: M3050-U1723.
DOI:10.1107/S1600536807057613

摘要

In the title compound, catena-poly[[dibenzyldichloridotin(IV)]-mu-1,4-bis(pyridin-3-ylmethoxy) benzene], [SnCl2-(C7H7)(2)(C18H16N2O2)](n), the dibenzyldichlorostannane molecules are linked by the neutral 1,4-bis(pyridin-3-ylmethoxy)benzene ligands to generate an infinite coordination polymer. Both the Sn atom and the linking ligand reside on centers of inversion. The Sn atom displays a distorted octahedral geometry that consists of two benzyl groups, two chloride ions and two N atoms from different 1,4-bis(pyridin-3-ylmethoxy) benzene ligands.