A new coordination tetramer of copper(I) iodide and benzyldimethylamine: tetra-mu(3)-iodido-tetrakis[(benzyldimethylamine-kappa N)copper(I)]

作者:Yang Shuying; Li Yuebao; Cui Yujie; Pan Jianguo*
来源:Acta Crystallographica Section E-Structure Reports Online, 2009, 65(8): M906-U796.
DOI:10.1107/S1600536809026208

摘要

The title compound, [Cu4I4(C9H13N)(4)], has a distorted cubane-like [Cu4I4] core structure. Each Cu-I atom is tetra-hedrally coordinated by three I atoms and one N atom of an benzyldimethylamine ligand. Each I atom acts as a mu(3)-ligand, linking three Cu-I atoms. The Cu-I bond distances vary between 2.6328 (7) and 2.7121 (6) angstrom, while the Cu-N bond distances vary between 2.107 (3) and 2.122 (3) angstrom.

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