Gas-phase water-mediated equilibrium between methylglyoxal and its geminal diol

作者：Axson Jessica L; Takahashi Kaito; De Haan David O; Vaida Veronica^*

来源：Proceedings of the National Academy of Sciences of the United States of America, 2010, 107(15): 6687-6692.

DOI：10.1073/pnas.0912121107

• hydration
• equilibrium constant
• water clusters

In aqueous solution, aldehydes, and to a lesser extent ketones, hydrate to form geminal diols. We investigate the hydration of methylglyoxal (MG) in the gas phase, a process not previously considered to occur in water-restricted environments. In this study, we spectroscopically identified methylglyoxal diol (MGD) and obtained the gas-phase partial pressures of MG and MGD. These results, in conjunction with the relative humidity, were used to obtain the equilibrium constant, K-P, for the water-mediated hydration of MG in the gas phase. The Gibbs free energy for this process, Delta G degrees, obtained as a result, suggests a larger than expected gas-phase diol concentration. This may have significant implications for understanding the role of organics in atmospheric chemistry.

• 出版日期2010-4-13