科研之友
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摘要
The title compound, [Fe-4(C6H6NS)(CH3S)S(CO)(11)], comprises two butterfly-shaped sub-cluster cores, Fe2S2N and Fe2S2, joined together by a spiro-type mu(4)-S atom. The (pyridin-2-yl) methanethiolate ligand is attached to the Fe-2(CO)(5) unit in a mu-kappa N:kappa S-2 mode, and the methanethiolate ligand is coordinated to the Fe-2(CO)(6) unit in a mu-kappa S-2 fashion.
