A Cobalt Supramolecular Compound Constructed from 4,6-Di(1-imidazolyl)-1,3,5-triazine-2-one: Synthesis, Characterization and Magnetic Property

作者：Zheng Tianxing; Han Yide; Liu Ningning^*

来源：Chemical Research in Chinese Universities, 2016, 32(2): 184-187.

DOI：10.1007/s40242-016-5456-4

• Coordination polymer
• Supramolecular architecture
• Solvothermal
• Magnetic property

A cobalt(II) coordination polymer, [Co(dimto)(2)(H2O)(2)]center dot 4H(2)O[1, dimto=4,6-di(1-imidazolyl)-1,3,5-triazine-2-one], has been prepared under solvothermal condition. Single-crystal structural analysis reveals that compound 1 crystallizes in the orthorhombic space group Ibca(No.73) with a=1.80696(12) nm, b=1.93224(11) nm, c=1.36798(10) nm, V=4.7763(5) nm(3) and R-1=0.0438. Compound 1 is a 3D supramolecular architecture composed of 1D wave-like chains with hydrogen bonds and pi-pi interactions. Compound 1 was further characterized by powder X-ray diffraction(PXRD), infrared(IR) spectroscopy, thermogravimertic analysis(TG) and elemental analysis. Additionally, the magnetic property of compound 1 was also investigated.

• 出版日期2016-4
• 单位辽宁石油化工大学; 东北大学