A new nitrogen-containing carbon nanoparticle coated stainless steel fiber for selective solid-phase microextraction of ultraviolet filters

作者：Wang Tian e; Guo Mei; Song Wen lan; Zhang Yi da; Du Xin zhen^*

来源：Analytical Methods, 2015, 7(8): 3385-3394.

DOI：10.1039/c5ay00009b

A new nitrogen-containing carbon nanoparticle (N-CNP) coated fiber was developed for solid phase microextraction (SPME) with direct electrodeposition of a polyaniline coating on etched stainless steel wire using a potentiostatic technique followed by carbonization at 500 degrees C under a nitrogen atmosphere. The extraction performance of the N-CNP coating was investigated towards polycyclic aromatic hydrocarbons (PAHs), ultraviolet (UV) filters and phthalate acid esters (PAEs) in water samples coupled to high performance liquid chromatography with UV detection (HPLC-UV). This N-CNP coating shows excellent selectivity for UV filters compared to that for PAHs and PAEs. Under optimized conditions, the linearity of UV filters was in the range of 0.02-200 mu g L-1 with a corresponding correlation coefficient of 0.9921-0.9993. The recoveries ranged from 89.2% to 119%. The relative standard deviations of a single fiber were between 4.83% and 7.82% (n = 5) and fiber-to-fiber were between 7.94% and 10.14% (S/N = 3). Their limits of detection and the limits of quantitation ranged from 0.006-0.203 mu g L-1 and 0.02-0.67 mu g L-1, respectively. The proposed SPME-HPLC-UV procedure was successfully used for the selective concentration and sensitive determination of UV filters in environmental water samples. Furthermore, this new robust fiber was easily prepared in a reproducible manner.

• 出版日期2015
• 单位西北师范大学