A ligand-free and base-free copper catalyzed reaction: arylation of ammonia and primary amines as their acetate salts

作者：Siddegowda Maravanahalli S; Yathirajan Hemmige S; Ramakrishna Ramesha A^*

来源：Tetrahedron Letters, 2012, 53(39): 5219-5222.

DOI：10.1016/j.tetlet.2012.07.048

• Ammonium acetate
• Copper
• Amines
• Arylation
• Primary amines

A ligand-free, base-free copper catalyzed arylation of ammonia and primary amines as their corresponding acetate salts are established. The Carboxylate group is believed to be catalyzing the arylation of ammonia. This reaction is specific for primary amines.

• 出版日期2012-9-26