A new strategy for the synthesis of polytrithiocarbonates using a polymeric support system

作者：You YZ; Hong CY; Pan CY^*

来源：Macromolecular Rapid Communications, 2002, 23(13): 776-780.

DOI：10.1002/1521-3927(20020901)23:13<776::AID-MARC776>3.0.CO;2-X

• nucleophilic substitution
• polymeric supports
• polytrithiocarbonates
• trithiocarbonate anion

A new polymerization strategy, consisting of nucleophilic substitution reaction between CS32-, immobilized on a polymeric support, and dimethyl a,a'-dibromoalkylanedioate in solution, leads to the formation of polytrithiocarbonates. When n = 0, 1 in CH3OOC-CHBr(CH2)nCHBrCOOCH(3) (a,a'-dibromoalkylanedioate), only five- or six-membered cyclic trithiocarbonates were obtained; n greater than or equal to 2 resulted in the formation of polytrithiocarbonates.

• 出版日期2002-9-30
• 单位中国科学技术大学