New porphyrinoids: Vanadyl(IV) complexes of meso-aryl-substituted corrphycene and 10-oxocorrole ligands

作者：Broering Martin; Hell Christian; Bregier Frederique; Burghaus Olaf; Tejero Esther Consul

来源：Inorganic Chemistry, 2007, 46(14): 5477-5479.

DOI：10.1021/ic700844p

Rare vanadyl corrphycene and vanadyl 10-oxocorrole complexes were obtained via an oxidative macrocyclization process by the treatment of 6,6 '-di-p-tolyl-2,2 '-bidipyrrin with VO(acac)(2) in a hot dioxygen atmosphere. The geometric and electronic structures of the new porpyhrinoids were determined and showed the dependency of the spectral pattern from the aromaticity of the macrocyclic ligand.

• 出版日期2007-7-9