Azido(benzoylacetonato-kappa O-2,O ')[1-phenyl-3-(2-pyridylmethylimino)but-1-en-1-olato-kappa N-3,N ',O]cobalt(III)

作者：Datta Amitabha; Sie Ming Han; Huang Jui Hsien; Lee Hon Man^*

来源：ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66: M248-U214.

DOI：10.1107/S1600536810003338

In the title complex, [Co(C16H15N2O)(C10H9O2)(N-3)], the Co-II atom adopts an octahedral coordination geometry by a tridentate Schiff base, a bidentate benzoylacetonate and an azide ligand. The imine N atom of the tridentate ligand is trans to the benzoyl O atom of the bidentate ligand and the azide ligand is trans to the acetyl O atom of the bidentate ligand. Non-classical intramolecular C-aryl-H center dot center dot center dot O hydrogen bonds are present in the structure.

• 出版日期2010-3