A New Route to Atactic Polypropylene: The Second Life of Premetallocene Homogeneous Polymerization Catalyst

作者:Kissin Yury V*; Rishina Laura A; Lalayan Svetlana S; Krasheninnikov Vadim G
来源:Journal of Polymer Science Part A: Polymer Chemistry , 2015, 53(18): 2124-2131.
DOI:10.1002/pola.27651

摘要

Amorphous atactic polypropylene (PP) with an average molecular weight of 50,000-100,000 is produced by polymerizing propylene with a ternary Ti(Oiso-Pr)(4) - AlEt2Cl/MgBu2 catalyst at 30-50 degrees C. Main advantages of this catalyst compared with other catalysts capable of nearly exclusively producing atactic PP (such as some heterogeneous Ziegler-Natta, metallocene and postmetallocene catalysts) are high activity, low cost and the ease of use: the catalyst is prepared in situ from three commercially available compounds readily soluble in aliphatic and aromatic hydrocarbons.

  • 出版日期2015-9-15
  • 单位rutgers