Layer-Block Dendrimers with Alternating Thienylenevinylene and Phenylenevinylene Units

作者：Hadad Caroline; Garcia Martinez Joaquin C; Rodriguez Lopez Julian^*

来源：Journal of Organic Chemistry, 2012, 77(14): 6223-6230.

DOI：10.1021/jo301054w

A series of new hybrid, layer-block pi-conjugated dendrons and dendrimers with alternating thienylenevinylene and phenylenevinylene units has been prepared by means of an orthogonal and convergent-growth methodology that made use of the Horner-Wadsworth-Emmons (HWE) reaction. The placement of the thiophene and benzene rings can be accurately controlled to afford a large variety of dendritic structures, although access to compounds of high generation proved difficult. The optical properties of the synthesized dendrimers were determined by UV/vis and fluorescence spectroscopy, and the influence of the generation and nature of the core on the behavior of these materials was evaluated.

• 出版日期2012-7-20