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摘要
A novel lanthanum-molybdenum coordination polymer [La(H2O)(3)(MoO4)](2)C2O4 (1) has been synthesized from hydrothermal reactions. Single crystal structure analysis reveals that compound 1 has a 3D framework structure consisting of double-metal centers of nine-coordinated La(III) and four-coordinated Mo(VI), and bridging oxalate ligands (C2O42-). Interestingly, in situ formation of ligand from L-Histidine to oxalate is observed. Furthermore, the fluorescence property of the polymer has also been investigated.
- 出版日期2014-6-25
- 单位河北师范大学
