Aqueous preparation of surfactant-free copper selenide nanowires

作者:Chen, Xinqi; Li, Zhen*; Yang, Jianping; Sun, Qiao; Dou, Shixue
来源:Journal of Colloid and Interface Science, 2015, 442: 140-146.
DOI:10.1016/j.jcis.2014.11.052

摘要

Uniform surfactant-free copper selenide (Cu2-xSe) nanowires were prepared via an aqueous route. The effects of reaction parameters such as Cu/Se precursor ratio, Se/NaOH ratio, and reaction time on the formation of nanowires were comprehensively investigated. The results show that Cu2-xSe nanowires were formed through the assembling of CuSe nanoplates, accompanied by their self-redox reactions. The resultant Cu2-xSe nanowires were explored as a potential thermoelectric candidate in comparison with commercial copper selenide powder. Both synthetic and commercial samples have a similar performance and their figures of merit are 0.29 and 0.38 at 750 K, respectively.