Antiradical activity of 2-substituted 4-(1,3-thiazol-4-yl)-1,2-dihydroxybenzenes

作者：Odaryuk V V^*; Khlestov N M; Burakov N I; Kanibolotskaya L V; Odaryuk I D; Shendrik A N

来源：Russian Journal of General Chemistry, 2014, 84(2): 268-271.

DOI：10.1134/S1070363214020182

Antiradical activity of 2-substituted 4-(1,3-thiazol-4-yl)-1,2-dihydroxybenzenes in the reaction with 1,1-diphenyl-2-picrylhydrazyl stable radical has been studied. Kinetic parameters of the process have been determined. Energy of homolytic dissosiation of the O-H bond of the studied compounds has been computed by DFT simulation in the 6-31G(p,d) basis set. The calculated bond energies correlate with the experimental rate constants.

• 出版日期2014-2