Development of a group contribution method for determination of viscosity of ionic liquids at atmospheric pressure

作者：Gharagheizi Farhad; Ilani Kashkouli Poorandokht; Mohammadi Amir H^*; Ramjugernath Deresh; Richon Dominique

来源：Chemical Engineering Science, 2012, 80: 326-333.

DOI：10.1016/j.ces.2012.06.045

• Viscosity
• Ionic liquids
• Group contribution
• Model
• Database
• Estimation

In this study, a wide literature survey has been carried out to collect an extensive set of liquid viscosity data for ionic liquids (ILs). A data set consisting of 1672 viscosity values and comprising 443 ILs was collated from 204 different literature sources. Using this data set, a reliable group contribution method has been developed. The method employs a total of 46 sub-structures in addition to the temperature to predict the viscosity of ILs. In order to differentiate the effects of the anion and cation on the viscosity of ILs, 24 sub-structures related to the chemical structure of anions, and 22 sub-structures related to the chemical structure of cations were implemented. The proposed model produces a low average relative deviation (AARD) of less than 6.4% taking into consideration all 1672 experimental data values.

• 出版日期2012-10-1