A kinetic consideration on the selective adsorption and molecular recognition by molecularly imprinted polymer

作者：Li Wuke; Li Songjun^*; Luo Gang; Ding Kerong

来源：Bulletin of the Korean Chemical Society, 2007, 28(8): 1346-1352.

• molecularly imprinted polymer
• adsorption
• kinetics

This article presents an original work on kinetically studying the selective adsorption and recognition by molecularly imprinted polymer (MIP). With S-naproxen as template, the imprinted polymer was prepared. The result indicates that the prepared polymer shows a more complicated sorption toward S-naproxen than toward its enantiomer R-naproxen. The rate constant in the case of template appears to be a variable. There are also significant deviations from the idealized Langmuir model. Related information indicates that these, in logic, can be a result of biomimic structural and functional complements between imprint and the template, which makes the polymer capable of selectively recognizing the imprint species.

• 出版日期2007-8-20
• 单位华中师范大学