A new fluorescent enhanced probe based on (E)-9-(2-nitrovinyl)-anthracene for the detection of bisulfite anions and its practical application

作者：Chao Jianbin^*; Liu Yuhong; Zhang Yan; Zhang Yongbin; Huo Fangjun; Yin Caixia; Wang Yu; Qin Liping

来源：Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy , 2015, 146: 33-37.

DOI：10.1016/j.saa.2015.03.074

• (E)-9-(2-nitrovinyl)-anthracene
• Fluorescent probe
• Bisulfite anion
• Detection limit

A new fluorescent enhanced probe based on (E)-9-(2-nitrovinyl)-anthracene is developed, which shows high selectivity and sensitivity for the detection of bisulfite anions at Na2HPO4 citric acid buffer solutions (pH 5.0). When addition of HSO3-, the fluorescence intensity is significantly enhanced and the probe displays apparent fluorescence color changes from non-fluorescence to blue under a UV lamp illumination, the solution color also changes from yellow to colorless. The detection limit is determined to be as low as 6.30 mu M. This offers another specific calorimetric and fluorescent probe for bisulfite anions detection, furthermore it is applied in detecting the level of bisulfite in sugar samples.

• 出版日期2015-7-5
• 单位中国科学院长春应用化学研究所; 山西大学