A Cyanide-Bridged Magnetically Switchable Cage with Encapsulated Water Molecules

作者:Wei Rong Jia; Shiga Takuya; Newton Graham N; Robinson David; Takeda Sadamu; Oshio Hiroki*
来源:Inorganic Chemistry, 2016, 55(23): 12114-12117.
DOI:10.1021/acs.inorgchem.6b02306

摘要

A cage complex, H2O@[Co5Fe4], was found to encapsulate two water molecules during its self assembly. The complex exhibited remarkable multi functionality, combining magnetic switching from the thermal electron-transfer-coupled spin transition of the cage host and dipolar reorientational motion of the confined water, as evidenced by permittivity measurements, density functional theory calculations, and solidstate H-2 NMR spectra.

  • 出版日期2016-12-5

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