Ultrafast Nanocrystals Decorated Micromotors for On-Site Dynamic Chemical Processes

作者：Jurado Sanchez B^*; Wang J; Escarpa A

来源：ACS Applied Materials & Interfaces, 2016, 8(30): 19618-19625.

DOI：10.1021/acsami.6b05824

• micro/nanomotors
• self-propulsion
• nanocrystals
• quantum dots
• cation-exchange
• photocatalytic degradation

CdS-polyaniline-Pt and ZnS-polyaniline-Pt micro motors have been synthesized and characterized. The nanocrystals are generated "in situ" during the template electrosynthesis of the micromotors while being simultaneously trapped in the polymeric network, generating a hybrid structure. The presence of nanocrystal "edges" in the inner polyaniline layer result in a rough Pt catalytic surface and enhanced electron transfer for highly efficient bubble propulsion at remarkable speeds of over 2500 mu m/s. The incorporation of CdS and ZnS nanocrystals impart several attractive functions, including cation-exchange based chemical transformation capabilities and enhanced photo catalytic performance. The remarkable ion-exchange properties of ZnS-polyaniline (PANI)-Pt micromotors are illustrated for the cation exchange of heavy metals cations. The superior photo catalytic performance of CdS-PANI-Pt micromotors is used for the enhanced photocatalytic oxidation of bisphenol A. Such selfpropelled micromotors act as highly efficient dynamic platforms that offer significantly shorter and more efficient processes as compared with common static operations. The attractive properties of these micromotors will pave the way for diverse sensing, decontamination, energy generation, or electronic applications.

• 出版日期2016-8-3