Disulfide-Bridged (Mo3S11) Cluster Polymer: Molecular Dynamics and Application as Electrode Material for a Rechargeable Magnesium Battery

作者:Quang Duc Truong; Devaraju Murukanahally Kempaiah; Nguyen Duc N; Gambe Yoshiyuki; Nayuki Keiichiro; Sasaki Yoshikazu; Tran Phong D; Honma Itaru
来源:Nano Letters, 2016, 16(9): 5829-5835.
DOI:10.1021/acs.nanolett.6b02593

摘要

Exploring novel electrode materials is critical for the development of a next-generation rechargeable magnesium battery with high volumetric : capacity. Here, we showed that a distinct amorphous molybdenum sulfide, :being a coordination polymer of disulfide-bridged (Mo3S11) clusters, has great,potential as a rechargeable magnesium battery cathode.. This material provided good reversible capacity, attributed to its unique structure with high flexibility and capability of deformation upon Mg insertion. Free terminal disulfide moiety May: act as the:active site for reversible insertion and, extraction of magnesium.

  • 出版日期2016-9