A Self-Assembled Electro-Active M8L4 Cage Based on Tetrathiafulvalene Ligands

作者：Goeb Sebastien^*; Bivaud Sebastien; Croue Vincent; Vajpayee Vaishali; Allain Magali; Salle Marc

来源：Materials, 2014, 7(1): 611-622.

DOI：10.3390/ma7010611

• self-assembly
• metalla-cages
• metal-driven
• tetrathiafulvalene
• redox

Two self-assembled redox-active cages are presented. They are obtained by coordination-driven self-assembly of a tetra-pyridile tetrathiafulvalene ligand with cis-M(dppf)(OTf)(2) (M = Pd or Pt; dppf = 1,1%26apos;-bis(diphenylphosphino)ferrocene; OTf = trifluoromethane-sulfonate) complexes. Both species are fully characterized and are constituted of 12 electro-active subunits that can be reversibly oxidized.

• 出版日期2014-1