Water compatibility and organic transformations of organo-Zintl deltahedral clusters

作者:Hull Michael W*; Sevov Slavi C
来源:Chemical Communications, 2012, 48(62): 7720-7722.
DOI:10.1039/c2cc32263c

摘要

We report the remarkable stability of di-substituted organo-Zintl deltahedral clusters in the presence of water. This has been exploited in a reaction at the organic substituents of the cluster which produces water as a by-product. Also reported are the synthesis, characterization, and crystal structure of [K-krypt](2)-[Ge-9-(CH=CH-CH2NH2)(2)] involved in the reaction.

  • 出版日期2012