科研之友
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摘要
In the title complex, a centrosymmetric carboxylate-bridged tetranuclear zinc-cerium derivative, [Zn2Ce2(C4H5O2)(10)(C5H5N)(2)(H2O)(2)], the Ce-III and Zn-II ions are bridged by two bidentate carboxylato groups [Ce...Zn 4.139 (1) Angstrom], while the Ce ions are linked through the three bidentate carboxylate groups [Ce...Ce 4.430 (1) Angstrom]. The Ce atoms are nine-coordinate and the coordination polyhedron is a distorted tricapped trigonal prism. The Zn atoms are four-coordinate with a distorted tetrahedral geometry.
- 出版日期2004-9
- 单位浙江大学
