科研之友
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摘要
Tricoordinate boron with its vacant p-orbital is a potent pi-acceptor in conjugated organic molecules relevant to the construction of novel optoelectronic materials. The new concept of kinetic stabilization by structural constraint offers a powerful strategy that enables the synthesis of hitherto unprecedented boron-containing polycyclic aromatic hydrocarbons. These new planarized organoboranes feature intriguing photophysical and self-assembly properties and hence are particularly interesting for application in organic optoelectronic devices.
- 出版日期2013
