摘要

Molar volume, viscosity and conductance of solutions of sodium bromide in different mol percent of methanol in N,N-dimethylformamide have been calculated from density, viscosity and conductance data respectively at temperatures 298.15, 303.15, 308.15 and 313.15 K. The structure breaker behaviour of sodium bromide in 0.1070 mol percent of methanol in N,N-dimethylformamide solutions is inferred from the sign of (partial derivative(2)Phi(0)(v)/partial derivative T(2))(P), dB/dT and temperature coefficient of Walden product i.e. d(Lambda(0)(m)eta(0))/dT values.

  • 出版日期2010-7