An open metal-organic framework based on Cu3-triad triangular units and templated by double Wells-Dawson anions

作者：Wang, Dan-dan; Peng, Jun^*; Zhang, Peng-peng; Wang, Xiang; Zhu, Min; Liu, Ming-guan; Meng, Cui-li; Alimaje, Kundawlet

来源：Inorganic Chemistry Communications, 2011, 14(12): 1911-1914.

DOI：10.1016/j.inoche.2011.09.009

• Polyoxometalate
• Double templates
• Cu-3-triad triangular unit
• Electrochemical property

A novel double-Dawson-anion-templated, triangular trinuclear Cu-trz unit-based metal-organic framework [Cu-8(II)(trz)(6)(mu(3)-O)(2)(H2O)(12)][P2W18O62]center dot 4H(2)O (1) (Htrz=1,2,4-triazole), has been hydrothermally synthesized and characterized by routine methods. Compound 1 is the first example of the Cu-3-triad triangular unit-based three-dimensional (3D) metal-organic framework templated by double [P2W18O62](6-) polyoxoanions. Furthermore, the electrochemical property of compound 1 has been studied.

• 出版日期2011-12
• 单位东北师范大学