Aerobic Copper Catalysis for Tandem Oxy-N-alkenylation of [1,2,3]Triazolo[1,5-a]pyridines

作者:Pankajakshan, Sreekumar*; Ang, Wei Li; Sreejith, Sivarampanicker; Stuparu, Mihaiela Corina; Loh, Teck-Peng*
来源:Advanced Synthesis & Catalysis, 2016, 358(19): 3034-3038.
DOI:10.1002/adsc.201600580

摘要

N-Alkenylated triazolinone ylides were generated through copper-catalyzed oxy-N-alkeny-lation of triazolopyridines. The mechanistic course of this aerobic tandem reaction has been experimentally elucidated and primary photophysical data of the ylide products are also given.