LITHIUM DIISOPROPYLAMIDE (LDA) AS AN EFFICIENT REDUCING AGENT FOR THIOKETONES-MECHANISTIC CONSIDERATION

作者：Jasinski Marcin; Mloston Grzegorz^*; Gebert Andreas; Heimgartner Heinz

来源：Phosphorus, Sulfur, and Silicon and the Related Elements, 2015, 190(8): 1281-1284.

DOI：10.1080/10426507.2015.1012201

• Thioketones
• LDA
• hydride transfer
• sulfides
• reaction mechanisms

Treatment of thiocarbonyl compounds with excess of lithium diisopropylamide (LDA) leads to corresponding thiols or sulfides depending on the work-up procedure. The mechanistic scenario for this unusual reduction pathway is discussed.

• 出版日期2015-8-3