Novel planar and sandwich-type complexes of substituted tetrathieno[2,3-b] porphyrazine: Synthesis and investigation of properties

作者：Dubinina Tatiana V^*; Dyumaeva Dania V; Trashin Stanislav A; Sedova Marina V; Dudnik Alexander S; Borisova Natalia E; Tomilova Larisa G; Zefirov Nikolay S

来源：Dyes and Pigments, 2013, 96(3): 699-704.

DOI：10.1016/j.dyepig.2012.11.008

• Porphyrazine
• Thiophene
• Triple-decker complex
• Lanthanide
• AFM
• NMR

An efficient synthetic approach to a novel substituted tetrathieno[2,3-b]porphyrazine, its Mg, Zn, Lu complexes and a Lu triple-decker complex was developed. Spectral properties and aggregation phenomena of the target compounds were investigated by UV/Vis spectroscopy and atomic force microscopy (AFM). Electrochromic behaviour of the Zn complex was studied by electrochemistry and spectroelectrochemistry.

• 出版日期2013-3