Aquachlorido(4-methylbenzoato-kappa O)-(1,10-phenanthroline-kappa N-2,N ')copper(II)

作者：Song Wen Dong^*; Wang Hao; Miao Yan Li

来源：Acta Crystallographica Section E-Structure Reports Online, 2008, 64: M716-U897.

DOI：10.1107/S1600536808010945

In the title mononuclear complex, [Cu(C8H7O2)Cl(C12H8N2)-(H2O)], the Cu-II atom is coordinated by one carboxylate O atom from a monodentate 4-methylbenzoate ligand, two N atoms from the 1,10-phenanthroline ligand, one chloride ion and one water molecule in a square-pyramidal geometry. The crystal structure exhibits inter- and intramolecular C-H center dot center dot center dot Cl, C-H center dot center dot center dot O, O-H center dot center dot center dot Cl and O-H center dot center dot center dot O hydrogen bonds, as well as C-H center dot center dot center dot pi interactions of phenanthroline and methyl H atoms towards the pi-systems of neighboring 4-methyl-benzoate units and the pyridine rings of the phenanthroline system [centroid-centroid distances are 2.706 (2) and 2.992 (1) angstrom, respectively].

• 出版日期2008-5