Effect of kaolin-metal oxides core-shell pigments on the properties of styrene-butadiene rubber composites

作者：El Sabbagh S H; Ahmed N M^*; Ward A A

来源：Materials & Design, 2012, 40: 343-355.

DOI：10.1016/j.matdes.2012.04.004

This study investigated the effects of core-shell kaolin-metal oxide pigments on the rheological, physico-mechanical and dielectric properties of styrene-butadiene rubber composites. In this way, newly prepared core-shell pigments based on kaolin as the core representing 90% of the whole pigment was covered with different metal oxides (CaO, MgO and CaO center dot MgO) comprising the shell which represents only 10% of the prepared pigments were incorporated with different concentrations in styrene-butadiene (SBR) rubber composites. Studying the different properties of pigmented and unpigmented SBR composites were done. Scanning electron microscopy (SEM) was used to feature out the surface morphology. Addition of the new pigments increased the tensile strength and strain energy, while elastic modulus was decreased. This study revealed that there is a significant effect of the new prepared pigments on SBR properties and the optimum pigment loading was 40 phr for CaO/kaolin, while it was 2.5 phr for MgO/kaolin. The dielectric results also showed that, the values of epsilon' (relative permittivity) and epsilon '' (dielectric loss) increased with increasing core shell content. Moreover, the samples containing MgO/kaolin and MgO center dot CaO/kaolin showed promising dielectric properties with low relative permittivity and electrical insulating properties. The different measurements showed good agreement in their results.

• 出版日期2012-9