A new pyrene-based Schiff-base: A selective colorimetric and fluorescent chemosensor for detection of Cu(II) and Fe(III)

作者：Bhorge Yeshwant Ramchandra; Tsai Haw Tyng; Huang Keh Feng; Pape Albert J; Janaki Sudhakar Narasimha; Yen Yao Pin^*

来源：Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy , 2014, 130: 7-12.

DOI：10.1016/j.saa.2014.03.110

• Chemosensor
• Cu2+ and Fe3+ ions
• Pyrene derivative
• Colorimetric
• Fluorescence
• Cell imaging

A new receptor 1 was prepared, for the detection of Cu2+ and Fe3+ in solutions as a colorimetric and fluorescent sensor, respectively. Receptor 1 shows highly selective and sensitive recognition toward Cu2+ and Fe3+ by naked eye UV-Vis and fluorescent color changes in aqueous solution (DMSO/H2O = 8/2, v/v), respectively. The sensitivity toward Cu2+ or Fe3+ was not interfered with by the presence of other metal ions such as Mg2+, Cd2+, Ag+, Zn2+, Ni2+, Co2+, Mn2+, Cr3+, Ca2+, Pb2+, K+, Fe2+, Li+ and Hg2+ ions. Receptor 1 can be used for semi-quantitative recognition of Cu2+ ions at ppm level. The fluorescence microscopy experiments showed that the receptor is efficient for detection of Fe3+ in vitro, developing a good image of the biological organelles.

• 出版日期2014-9-15