科研之友
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摘要
The effect of benzoyl peroxide loading on the adhesion properties of cross-linked epoxidized natural rubber (ENR 25)-based adhesives was studied using gum rosin and petroresin as tackifiers. Toluene and polyethylene terephthalate (PET) were used as solvent and coating substrate, respectively. The adhesion properties were determined by a Lloyd adhesion tester operating at 30 cm min(-1). Results indicate that the loop tack and peel strength of gum rosin and petroresin pass through a maximum value at 2 parts per hundred parts of rubber (phr) and 3 phr benzoyl peroxide concentration, respectively, an observation which is attributed to the optimum cross-linking of ENR 25 where optimum, cohesive and adhesive strength is obtained. The shear strength, however, increases steadily with increasing benzoyl peroxide loading due to the steady increase in the cohesive strength. At the optimum benzoyl peroxide concentration, the petroresin-based adhesive consistently exhibits higher adhesion properties compared to that of gum rosin-based adhesives. The adhesion properties of both adhesive systems increase with increasing coating thickness.
- 出版日期2014
