Homopolymerization of Ethylene, 1-Hexene, Styrene and Copolymerization of Styrene With 1,3-Cyclohexadiene Using (eta(5)-Tetramethylcyclopentadienyl)dimethylsilyl(N-Ar')amido-TiCl2/MAO (Ar'=6-(2-(Diethylboryl)phenyl)pyrid-2-yl, Biphen-3-yl)

作者：Camadanli Sebnem^*; Decker Ulrich; Kuehnel Christa; Reinhardt Ingrid; Buchmeiser Michael R

来源：Molecules, 2011, 16(1): 567-582.

DOI：10.3390/molecules16010567

• constrained geometry catalyst
• olefin
• homopolymerization
• copolymerization

The propensity of a half-sandwich (eta 5-tetramethylcyclopentadienyl) dimethylsilylamido Ti-IV-based catalyst bearing an auxiliary diethylboryl-protected pyridyl moiety (Ti-8), activated by methylaluminoxane (MAO) to homopolymerize alpha-olefins such as ethylene, 1-hexene and styrene as well as to copolymerize styrene with 1,3-cyclohexadiene is described. The reactivity of Ti-8 was investigated in comparison to a 6-(2-(diethylboryl)phenyl)pyrid-2-yl-free analogue (Ti- 3).

• 出版日期2011-1