A Synthesis of the Carbon Skeleton of Maoecrystal V

作者：Krawczuk Paul J; Schoene Niklas; Baran Phil S^*

来源：Organic Letters, 2009, 11(21): 4774-4776.

DOI：10.1021/ol901963v

An enantioselective synthesis of the maoecrystal V (1) carbon skeleton is described. The key transformations include arylation of a 1,3-dicarbonyl compound with a triarylbismuth(V) dichloride species, oxidative dearomatization of a phenol, and a subsequent intramolecular Diels-Alder reaction.

• 出版日期2009-11-5